Prediction of Vapor-Liquid Equilibrium of Binary Systems

Prediction of Liquid-Liquid Equilibria of Binary Systems Containing Alcohols Using EoS-GE Models

Liquid - Vapor Equilibrium/Distillation

Background The volatility of a compound is its ability to change into a vapor, or to evaporate at a particular temperature and pressure. The normal boiling point of a liquid usually allows comparison of its volatility to other materials, with lower boiling points indicating greater volatility, but this may be affected somewhat by the presence of other materials. Comparison of the concentration ...

Prediction of Vapor-Liquid Equilibria Using CEOS /GE Models

The present study investigates the use of different GE mixing rules in cubic equations of state for prediction of phase behavior of multicomponent hydrocarbon systems. To predict VLE data in multicomponent symmetric and asymmetric mixtures such as systems that contain light gases (nitrogen, carbon dioxide, etc.) and heavy hydrocarbons, the SRK equation of state has been combined with excess Gib...

Pressure Dependence of Liquid Vapor Pressure: An Improved Gibbs Prediction

A new model for the vapor phase of a pressurized liquid called "the cluster model: which is originally introduced in this work, along with an accurate equation of state for the liquid phase called the LIR, is used to derive an accurate equation for the vapor pressure of liquid as a function of external pressure. The chemical Potential of both phase have been found to be in good agreement wi...

Determination of Binary Vapor Liquid Equilibria (vle) of Reactive Systems

The simulation of reactive distillation processes requires binary phase equilibrium data and information about the reaction kinetics and equilibrium. The phase equilibrium data for the binary reacting sub-systems are difficult to measure experimentally since the products of reaction affect the binary equilibrium as soon as they are formed. A novel apparatus has been constructed to measure these...